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The effect of ph on aniline removal from water using hydrophobic and ion-exchange membranes

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datacite.rights.accessrightshttp://purl.org/coar/access_right/c_abf2
dc.contributor.authorFilian, Karla
dc.contributor.authorMendez-Ruiz, Jonathan
dc.contributor.authorGarces, Daniel
dc.contributor.authorReveychuk, Kateryna
dc.contributor.authorMa, Lingshan
dc.contributor.authorMelendez, Jesus R.
dc.contributor.authorCornelissen, Emile
dc.contributor.authorValverde-Armas, Priscila E.
dc.contributor.authorGutierrez, Leo
dc.contributor.authorDíaz Mendoza, Claudia Patricia
dc.date.accessioned2025-04-03T21:37:45Z
dc.date.issued2025-02-14
dc.date.submitted2025-03-09
dc.descriptionContiene gráficos, tablas
dc.description.abstractThe presence of aniline, a toxic aromatic amine, has been recorded in different industrial wastewaters. This study aims to investigate the transport of charged and neutral aniline species in aqueous solutions through hydrophobic and ion-exchange membranes (IEMs). Hydrophobic polyoctylmethylsiloxane (POMS) and polydimethylsiloxane (PDMS) membranes and cationic (CEMs) and anionic (AEMs) exchange membranes were tested using diffusion cells and electrodialysis (ED). Diffusion experiments showed that neutral aniline removal reached 90% with POMS and 100% with PDMS due to the concentration gradient between feed (pH = 10) and receiving (pH = 3) solutions. For IEMs, neutral aniline exhibited a faster transport than charged species, with neutral-to-charged transport ratios of 6.6:1 for AEMs and 3.2:1 for CEMs, type I. During ED experiments, an external electric potential increased the charged aniline transport, achieving higher initial fluxes (124.7 mmol·m2·h−1 at pH 4) compared to neutral aniline (43.6 and 53.2 mmol·m2·h−1 for AEMs and CEMs, type I). ED also demonstrated that charged aniline can be removed up to 97% using IEMs. These findings demonstrate the effectiveness of hydrophobic and IEMs in removing aniline, providing insights into its transport mechanism, contributing to the optimization of membrane technologies in treating industrial wastewater effluents, and environmental sustainability.
dc.format.extent16 páginas
dc.format.mimetypeapplication/pdf
dc.identifier.citationFilian, K., Mendez-Ruiz, J. I., Garces, D., Reveychuk, K., Ma, L., Melendez, J. R., ... & Gutierrez, L. (2025). The Effect of pH on Aniline Removal from Water Using Hydrophobic and Ion-Exchange Membranes. Water, 17(4), 547.
dc.identifier.instnameUniversidad Tecnológica de Bolívar
dc.identifier.reponameRepositorio Universidad Tecnológica de Bolívar
dc.identifier.urihttps://hdl.handle.net/20.500.12585/13261
dc.identifier.urlhttps://www.mdpi.com/2073-4441/17/4/547
dc.language.isoeng
dc.publisher.disciplineIngeniería Ambiental
dc.publisher.placeCartagena de Indias
dc.publisher.sedeCampus Tecnológico
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dc.rightsCC0 1.0 Universalen
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/publicdomain/zero/1.0/
dc.sourceWater
dc.subject.lembAniline
dc.subject.lembHydrophobic membranes
dc.subject.lembElectrical gradient
dc.subject.lembIon-exchange membranes
dc.subject.proposalAniline
dc.subject.proposalHydrophobic surfaces
dc.subject.proposalIon exchange resins
dc.titleThe effect of ph on aniline removal from water using hydrophobic and ion-exchange membranes
dc.typeArtículo de revistaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1spa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.hasversioninfo:eu-repo/semantics/publishedVersion
dspace.entity.typePublication
oaire.resourcetypehttp://purl.org/coar/resource_type/c_2df8fbb1
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
relation.isAuthorOfPublicationeee59a8f-a66e-4e21-8506-5479f9a90214
relation.isAuthorOfPublication.latestForDiscoveryeee59a8f-a66e-4e21-8506-5479f9a90214

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