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Use of a 416B-type central-hybrid experimental design to evaluate the synthesis conditions of TiO2/biochar composites on the solid-state photocatalytic degradation of polypropylene-plastic films

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datacite.rights.accessrightshttp://purl.org/coar/access_right/c_abf2
dc.audiencePúblico general
dc.contributor.authorMedina Guerrero, Astrid del Rosario
dc.contributor.authorHernández Ramírez, Aracely
dc.contributor.authorVázquez Rodríguez, Sofía
dc.contributor.authorColina Márquez, José Ángel
dc.contributor.authorMachuca Martínez, Fiderman
dc.contributor.authorBarraza Burgos, Juan
dc.contributor.authorRoa Espinosa, Aicardo
dc.contributor.authorGunasekaran, Sundaram
dc.contributor.authorCastilla Caballero, Deyler Rafael
dc.contributor.otherSundaram
dc.coverage.temporal2017-2025
dc.date.accessioned2025-03-21T13:42:18Z
dc.date.available2025-03-21T13:42:18Z
dc.date.issued2025-03-06
dc.date.submitted2025-03-20
dc.description.abstractThis study presents an innovative application of solid-state photocatalysis using environmentally friendly TiO2/biochar composites to degrade polypropylene (PP) films and reduce plastic pollution. Biochar, derived from coconut shells via controlled pyrolysis, was combined with TiO2 to enhance photocatalytic activity. A 416B-type Central-Hybrid Experimental Design was used to optimize synthesis parameters, revealing that biochar produced at 280°C with 4.1 % v/v oxygen and a TiO2/biochar weight ratio of 1.5 yields the best results. After 25 days of UV irradiation, films incorporated with TiO2/biochar composites exhibited an 8.7 % weight loss and a carbonyl index of 11.4—significantly surpassing pristine PP films. These findings demonstrate the potential of biochar as a sustainable solution to reduce nanotoxicity while boosting polymer degradation efficiency. This work contributes to the development of eco-friendly materials for mitigating plastic waste challenges.
dc.description.sponsorshipUniversidad del Valle Universidad de Wisconsin-Madison Universidad Autónoma de Nuevo León Soil-Net LLC Universidad Tecnológica de Bolívar
dc.description.tableofcontentsHighlights Abstract Graphical Abstract Keywords Nomenclature 1. Introduction 2. Materials and methods 3. Results and discussion 4. Conclusion CRediT authorship contribution statement Declaration of Competing Interest Acknowledgements Data availability References
dc.format.extent18 páginas
dc.format.mimetypeapplication/pdf
dc.identifier.citationCastilla-Caballero, D., Medina-Guerrero, A., Hernandez-Ramirez, A., Vazquez-Rodriguez, S., Colina-Márquez, J., Martínez, F. M., Barraza-Burgos, J., Roa-Espinosa, A., & Gunasekaran, S. (2025). Use of a 416B-type Central-Hybrid Experimental Design to evaluate the synthesis conditions of TiO2/biochar composites on the solid-state photocatalytic degradation of Polypropylene-plastic films. Applied Catalysis A: General, 120196. https://doi.org/10.1016/J.APCATA.2025.120196
dc.identifier.doi10.1016/j.apcata.2025.120196
dc.identifier.instnameUniversidad Tecnológica de Bolívar
dc.identifier.reponameRepositorio Universidad Tecnológica de Bolívar
dc.identifier.urihttps://hdl.handle.net/20.500.12585/13263
dc.language.isoeng
dc.publisher.disciplineIngeniería Ambiental
dc.publisher.facultyIngeniería
dc.publisher.placeCartagena de Indias
dc.publisher.sedeCampus Tecnológico
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 United Statesen
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/
dc.sourceJournal of Applied Catalysis A: General
dc.subject.armarcLEMB
dc.subject.keywordsSolid-State photocatalysis
dc.subject.keywordsTiO2/Biochar
dc.subject.keywordsPolypropylene
dc.subject.keywordsPlastic Pollution
dc.subject.keywords416B-type central-hybrid experimental design
dc.titleUse of a 416B-type central-hybrid experimental design to evaluate the synthesis conditions of TiO2/biochar composites on the solid-state photocatalytic degradation of polypropylene-plastic films
dc.type.driverinfo:eu-repo/semantics/article
dc.type.hasversioninfo:eu-repo/semantics/publishedVersion
dc.type.spahttp://purl.org/coar/resource_type/c_2df8fbb1
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